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BANDS OF $HNO_{2}$

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Ohio State University

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Fourier Transform infrared spectra of $HNO_{2}$ have been recorded with a Bruker IFS 120HR, at an instrumental resolution better than $0.003 cm^{-1}$. The pressure conditions of the various parent gases ($NO_{2}, NO$ and $H_{2}O$) are optimized during the experiments. The analysis of the $\nu_{1}$ band in $trans-HNO_{2}$ (1) will be reported. A very specific interaction pattern perturbing the $\nu_{1}=1$ level will be discussed. Preliminary results of the analysis of other bands in several wavelength regions will be also reported.

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(1) J.M. Guilmot, M. Carleer, M. Godefroid and M. Herman, submitted for publication.


Author Institution: Laboratoire de Chimie Physique Mol'eculaire, Universit'e Libre de Bruxelles CP.160

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