TORSION-ROTATION PERTURBATIONS IN ELECTRONIC SPECTROSCOPY. THE $S_{1}\leftarrow S_{0}$ SPECTRUM OF $2-METHYL-1-NAPHTHOL^{1}$
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Abstract
2-Methyl-1-naphthol (2M1HN) is an interesting molecule that exhibits motion along two low frequency coordinats, the torsional motion of the methyl group and rotational isomerism about the C-OH bond. Both motions are restricted by significant barriers; additionally, they couple to the overall rotational motion of the molecule and may also interact with each other. In this repot, we describe the fully resolved
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Author Institution: Department of Physics, University of Pittsburgh