HIGH-RESOLUTION INFRARED SPECTROSCOPY OF $HCN-Zn_{n}$ CLUSTERS
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Ohio State University
Abstract
Rotationally resolved infrared spectra have been obtained for the first time for transition metal complex-adsorbate systems. The zinc clusters are formed in helium d roplets, to which are added a single HCN molecule. The C-H stretches of the complexes have been measured for $HCN-Zn_{n}$, where n=1-4. The rotaional constants and di pole moments are reported and compared to ab initio calculations.
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Author Institution: Department of Chemistry, The University of North Carolina at Chapel Hill