LASER INDUCED FLUORESCENCE SPECTRA OF FREE-JET COOLED ORGANIC FREE RADICALS VINOXY, CYCLOPENTADIENYL, AND BENZYL
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Ohio State University
Abstract
The organic free radicals, vinoxy, cyclopentadienyl, and benzyl, have been produced in situ in a free jet expansion by excimer laser photolysis of suitable precursors. Rotationally resolved, laser induced fluorescence spectra, obtained downstream of the photolysis, show the gaseous radials are cold $ (\sim 10^{\circ} K)$. Details of the rotational analyses will be presented.
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Author Institution: Department of Chemistry, Illinois Institute of Technology Chicago; Department of Chemistry, Bell Laboratories